有机化学第四版(曾绍琼主编)第十六章元素有机化合物

《有机化学第四版(曾绍琼主编)第十六章元素有机化合物》由会员分享，可在线阅读，更多相关《有机化学第四版(曾绍琼主编)第十六章元素有机化合物（43页珍藏版）》请在文档大全上搜索。

1、 YULIN NORMAL UNIVERSITY YULIN NORMAL UNIVERSITY YULIN NORMAL UNIVERSITY YULIN NORMAL UNIVERSITYCNaCa YULIN NORMAL UNIVERSITY YULIN NORMAL UNIVERSITY YULIN NORMAL UNIVERSITY YULIN NORMAL UNIVERSITYNNTi(CH3)3乙醚乙醚 YULIN NORMAL UNIVERSITY无水乙醚无水乙醚N2，低温，低温 25 乙醚乙醚 YULIN NORMAL UNIVERSITY RLi YULIN NORMAL

2、 UNIVERSITY2+2KHKTHFS+SLin-C4H9-Li2+ 2KHKFe+ 2KClFeCl23RCH=CH2 + H-SiCl3H2PtCl6RCH2CH2SiCl3 YULIN NORMAL UNIVERSITY3RCH=CH2 + BH3(RCH2CH2)3BTHFO(1)H2O2(2)HO, H2O3RCH2CH2OH YULIN NORMAL UNIVERSITYNMeMeNMeMen-C4H9Li+ n-C4H9-LiTMEDATHFPh-CH2-Li +n-C4H10Ph-CH3 YULIN NORMAL UNIVERSITYOCH2OCH3HHSCH2HSCH3H

3、; YULIN NORMAL UNIVERSITYPh-S-CH3+n-C4H9-LiPh-S-CH2-Lin-C4H9-LiOCH3+OCH3Li YULIN NORMAL UNIVERSITYRLi + CO2RCOOLiH3ORCOOHRLi +R-H + R-SO-CH2LiR-SO-CH3RLi+Ph3P-CH2OCH3R-H + Ph3P=CHOCH3Cl YULIN NORMAL UNIVERSITYOEtOO+R-LiOEtOOLi+ R-HR-Li +ORRRCROLiRH3ORCROHR-COOH-CORH3OR3CCOCR3+ R3CLi-78( (干干冰冰丙丙酮酮) )

4、(R3C)3COLi(R3C)3COHHPhCOOHHCH3-Li(C2H5)2OHPhCHCH3OHPhCOOLiHCH3-LiHPhCHCH3LiOOLiH3O YULIN NORMAL UNIVERSITYO+Me2CuLiOMe(1)乙 醚 ， 0， 10min（ 2） H2OO+(CH2=CH)2CuLi(1)Ph-H(2)H3OO72% YULIN NORMAL UNIVERSITY YULIN NORMAL UNIVERSITY4BF3 OEt2+THF3NaBF4 + 2B2H6 + 4Et2O3NaBH4B2H6 + 2Et2O2Et2O BH3BR4 络合物 YULIN N